Solubility of organometallic complexes in supercritical carbon dioxide: A review
نویسندگان
چکیده
The solubility and solubility trends of organometallic complexes in supercritical carbon dioxide are reviewed. The influence of intermolecular forces, physical properties and the metal chelates on solubility is explored. A number of thermodynamic models used to predict the solubility behavior of organometallic complexes in supercritical carbon dioxide, and the advantages and limitations to these thermodynamic models are also discussed. 2012 Elsevier B.V. All rights reserved.
منابع مشابه
Solubility Prediction of Drugs in Supercritical Carbon Dioxide Using Artificial Neural Network
The descriptors computed by HyperChem® software were employed to represent the solubility of 40 drug molecules in supercritical carbon dioxide using an artificial neural network with the architecture of 15-4-1. The accuracy of the proposed method was evaluated by computing average of absolute error (AE) of calculated and experimental logarithm of solubilities. The AE (±SD) of data sets was 0.4 ...
متن کاملSolubility Prediction of High Molecular Weight n-Paraffins in Supercritical Carbon Dioxide
Solubility of high molecular weight n-paraffins in supercritical carbon dioxide has been a matter of interest to many researchers. However, not sufficient solubility experimental data are available although the methods by which the experimental data are obtained have many varieties. Utilizing cubic equations of state is an effective method for solubility prediction of n-paraffins in supercr...
متن کاملSolubility Prediction of Drugs in Supercritical Carbon Dioxide Using Artificial Neural Network
The descriptors computed by HyperChem® software were employed to represent the solubility of 40 drug molecules in supercritical carbon dioxide using an artificial neural network with the architecture of 15-4-1. The accuracy of the proposed method was evaluated by computing average of absolute error (AE) of calculated and experimental logarithm of solubilities. The AE (±SD) of data sets was 0.4 ...
متن کاملMeasurement and Modeling of Acridine Solubility in Supercritical Carbon Dioxide
Supercritical carbon dioxide has gained increasing attention in food and pharmaceutical processing owing to the fact that it is environmentally inexpensive, not flammable, essentially non-toxic, and it has a convenient critical point. Also, it has been attracting much attention in many fields, such as extraction of sensitive materials and pharmaceutical processing and polymerization processes. ...
متن کاملContinuous Synthesis of Oleyl Oleate in Supercritical Carbon Dioxide using Solid p-Toluenesulfonic Acid as Catalyst
Supercritical carbon dioxide (SC-CO2) was used as solvent to synthesize oleyl oleate as an analog of Jojoba oil from oleic acid and oleyl alcohol with high conversion (100%) of the acid into ester in a short time of 100 min. Utilizing a low cost solid catalyst, p-toluenesulfonic acid monohydrate (PTSA), the esterification reaction was performed, without any prior preparation step...
متن کامل